The prisoner, identified as Cedric Joseph Marks, was last seen in the area of the 800 block of North Loop 336 West, authorities said.
He was being extradited to face charges when he escaped. At the time, he was in a MI jail waiting to be extradited to Texas for allegedly breaking into Scott's house this past August.
Marks, who was arrested in MI last month on a burglary charge with the intent to commit another felony, was being extradited back to Bell County, Texas, in a prisoner transport van, according to ABC News.
Marks has three pending murder charges against him, authorities said, adding that he is considered to be "extremely risky".
Lt. Scott Spencer of the Conroe, Texas, Police Department, tweeted the news Sunday night.
He met Jenna Scott and, after a rough two years, she asked a judge for protection saying, "Marks threatens and hurts me and told me he had gotten away with murder before", records show. She also said she had her phone in her hand, and Marks took it from her and threw it. The protective order request was denied.
Police in Bloomington, Minnesota, say Marks remains a person of interest in the 2009 disappearance of April Pease, with whom he had a child.
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TV station KCEN reported that Marks was arrested in MI last month on a charge alleging he broke into the Temple, Texas, home of an ex-girlfriend, Jenna Scott, on August 21.
Another Marks ex-girlfriend is also missing.
The woman who voluntarily admitted she drove a Swearingin's auto to Austin with the hope of concealing it from law enforcement agencies was extradited to Bell County.
Maya Maxwell is charged with evidence tampering and is jailed in Bell County, Texas, on US$150,000 (NZ217,000) bond. He allegedly would threaten her every time she tried to break up with him, and even choked her until she lost consciousness twice.
Ginell McDonough, who is Marks' wife and the mother of two of his two children, is jailed in Muskegon County, Michigan, on an obstruction of justice charge. It was found abandoned in the city on January 6.
Maxwell had been in the Muskegon County Jail in MI since her January 11 arrest.
Jail records do not list an attorney for either woman.